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Title | 土壤中有機污染物濃度與實際污染強度關聯性研究計劃 |
Abstract | 瞭解污染物在不同介質的平衡分佈與作用機制,可以推估污染物在地下環境的宿命行為,進一步篩選出合適的整治技術,加速整治工作的進行。土壤是礦物質與SOM所組合成的雙重作用體,有機物對礦物質之作用是表面的吸附作用,呈現非直線型的等溫吸附線;SOM則是類似溶解機制的分配作用,產生直線型的等溫吸持線。在水溶液系統中,礦物質表面會優先被水分子所佔據,導致有機物對土壤的作用力主要是以分配到SOM為主。在氣相系統中 (通氣層),有機物對土壤的作用力會隨著相對濕度的變化而改變。對乾燥的土壤而言,礦物質表面的吸附為主要作用力;潮濕土壤則主要是分配到SOM的作用,其比例會隨著相對濕度而有所不同。有機物在整體土壤的濃度會和土壤有機質含量 (fom) 及污染物無因次分配係數 (Kom) 有關。基於潮濕土壤對有機物主要是分配作用,提出有效土壤污染濃度觀念,有機物在整體土壤的濃度與土壤有機質含量 (fom) 和污染物無因次分配係數 (Kom) 有關。土壤有機物污染濃度管制值必須考慮到土壤有機質成分,所訂定出來的地下水污染管制標準對不同的土壤才具有一致性。 |
EngTitle | Investigation of the correlation between the organic contamination level in soils and the actual con |
EngAbstract | Concentrations of organic contaminants in common productive soils based on the total soil mass give a misleading account of actual contamination effects. This is attributed to the fact that productive soils are essentially water-saturated, with the result that the soil uptake of organic compounds occurs principally by partition into the soil organic matter (SOM). The soil contamination intensity of a compound is governed by the concentration in the SOM (Com), i.e., the effective contamination level, rather than by the concentration in whole soil (Cs). This SOM-based index is considered timely needed for a evaluating the contamination effects of food crops grown in different soils and for establishing a dependable priority ranking for intended remediation of numerous contamination sites. |
ProjectYear | 103 |
SponsorOrg | 環檢所 |
ExecutingOrg | 中央大學環境工程研究所 |
PublicFullVersionURL | http://epq.epa.gov.tw/project/filedownload.aspx?fid=73426 |